Experimental measurements and modelling of vapor-liquid equilibria for four mixtures of 2,3,3,3-tetrafluoropropene (R1234yf) with 1,1,1,2-tetrafluoroethane (R134a) or 1,1-difluoroethane (R152a) or trans-1-chloro-3,3,3-Trifluoropropene (R1233zd(E)) or 2-Chloro-3,3,3-trifluoropropene (R1233xf) - Archive ouverte HAL Access content directly
Journal Articles International Journal of Refrigeration Year : 2022

Experimental measurements and modelling of vapor-liquid equilibria for four mixtures of 2,3,3,3-tetrafluoropropene (R1234yf) with 1,1,1,2-tetrafluoroethane (R134a) or 1,1-difluoroethane (R152a) or trans-1-chloro-3,3,3-Trifluoropropene (R1233zd(E)) or 2-Chloro-3,3,3-trifluoropropene (R1233xf)

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Abstract

Isothermal vapour-liquid equilibrium (VLE) for four binary systems involving R1234yf (R1234yf + R134a, R1234yf + R152a, R1234yf + R1233zd(E) and R1234yf + R1233xf) were measured at temperatures from 278.15 to 348.15 K. The experiments were conducted by means of a "static-analytic" apparatus with phase analysis via gas chromatography, with resulting uncertainties of 0.6 K for temperature, 8 kPa for pressure and a maximum of 0.007 for vapour and liquid mole fractions. The main advantage of the equipment is that vapour and liquid samples are taken from vapour and liquid phase by two capillary samplers (ROLSI®). The Peng Robinson Equation of state is considered to represent the experimental data. If possible, comparison between the new experimental data and prediction with REFPROP 10.0 software are realized.
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Dates and versions

hal-03668746 , version 1 (16-05-2022)

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Jamal El Abbadi, Christophe Coquelet, Alain Valtz, Céline Houriez. Experimental measurements and modelling of vapor-liquid equilibria for four mixtures of 2,3,3,3-tetrafluoropropene (R1234yf) with 1,1,1,2-tetrafluoroethane (R134a) or 1,1-difluoroethane (R152a) or trans-1-chloro-3,3,3-Trifluoropropene (R1233zd(E)) or 2-Chloro-3,3,3-trifluoropropene (R1233xf). International Journal of Refrigeration, 2022, 140, pp.172-185. ⟨10.1016/j.ijrefrig.2022.05.006⟩. ⟨hal-03668746⟩
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